Data archive for "Guest-driven control of folding in a crown-ether-functionalized ortho-phenylene"
| dc.contributor.author | Peddi, Sumalatha | |
| dc.contributor.author | Bookout, Molly C. | |
| dc.contributor.author | Vemuri, Gopi Nath | |
| dc.contributor.author | Hartley, C. Scott | |
| dc.date.accessioned | 2022-01-18T20:59:25Z | |
| dc.date.available | 2022-01-18T20:59:25Z | |
| dc.date.published | 2022 | |
| dc.description.abstract | A crown-ether-functionalized o-phenylene tetramer has been synthesized and coassembled with monotopic and ditopic, achiral and chiral secondary ammonium ion guests. NMR spectroscopy shows that the o-phenylene forms both 1:1 and 1:2 complexes with monotopic guests while remaining well-folded. Binding of an elongated ditopic guest, however, forces the o-phenylene to misfold by pulling the terminal rings apart. A chiral ditopic guest biases the o-phenylene twist sense. | en_US |
| dc.identifier.other | Peddi, S.; Bookout, M. C.; Vemuri, G. N.; Hartley, C. S. Guest-driven control of folding in a crown-ether-functionalized ortho-phenylene. J. Org. Chem. 2022, DOI: 10.1021/acs.joc.1c02605 | en_US |
| dc.identifier.uri | http://hdl.handle.net/2374.MIA/6803 | |
| dc.relation.isversionof | 10.1021/acs.joc.1c02605 | en_US |
| dc.rights | Attribution 3.0 United States | * |
| dc.rights.uri | http://creativecommons.org/licenses/by/3.0/us/ | * |
| dc.title | Data archive for "Guest-driven control of folding in a crown-ether-functionalized ortho-phenylene" | en_US |
| dc.type | Journal Article | en_US |