• Data archive for "Chemically fueled transient geometry changes in diphenic acids" 

  Jayalath, Isuru M.; Wang, Hehe; Mantel, Georgia; Kariyawasam, Lasith S.; Hartley, C. Scott

  Transient changes in molecular geometry are key to the function of many important biochemical systems. Here, we show that diphenic acids undergo out-of-equilibrium changes in dihedral angle when reacted with a carbodiimide ...

• Data archive for "ortho‐Phenylene‐based macrocyclic hydrocarbons assembled using olefin metathesis" 

  Kirinda, Viraj C.; Schrage, Briana R.; Ziegler, Christopher J.; Hartley, C. Scott

  While many foldamer systems reliably fold into well‐defined secondary structures, higher order structure remains a challenge. A simple strategy for the organization of folded subunits in space is to link them together ...

• Data archive for "Dissipative assembly of macrocycles comprising multiple transient bonds" 

  Hossain, Mohammad Mosharraf; Atkinson, Joshua L.; Hartley, C. Scott

  Dissipative (nonequilibrium) assembly powered by chemical fuels has great potential for the creation of new adaptive chemical systems. However, while molecular assembly at equilibrium is routinely used to prepare complex ...

• Data archive for "Structure–property effects in the generation of transient aqueous benzoic acid anhydrides by carbodiimide fuels" 

  Kariyawasam, Lasith S.; Kron, Julie C.; Jiang, Run; Sommer, André J.; Hartley, C. Scott

  The design of dissipative systems, which operate out-of-equilibrium by consuming chemical fuels, is challenging. As yet, there are a few examples of privileged fuel chemistries that can be broadly applied in abiotic systems ...

• Data archive for "Macrocycles of higher ortho-phenylenes: assembly and folding" 

  Kinney, Zacharias J.; Kirinda, Viraj C.; Hartley, C. Scott

  Higher-order structure in abiotic foldamer systems represents an important but largely unrealized goal. As one approach to this challenge, covalent assembly can be used to assemble macrocycles with foldamer subunits in ...

• Data archive for "Chemically fueled covalent crosslinking of polymer materials" 

  Zhang, Borui; Jayalath, Isuru M.; Ke, Jun; Sparks, Jessica L.; Hartley, C. Scott; Konkolewicz, Dominik

  Transiently crosslinked dynamic polymer networks are developed, using carbodiimide hydration to link carboxylic acids as anhydrides. From aqueous polymer solutions, non-equilibrium hydrogels are transiently formed, which ...

• Data archive for "Twist sense control in terminally functionalized ortho-phenylenes" 

  Hartley, C. Scott; Vemuri, Gopi Nath; Pandian, Rathiesh R.; Spinello, Brian J.; Stopler, Erika B.; Kinney, Zacharias J.

• Data archive for "Linker-Directed Assembly of Twisted ortho-Phenylene-Based Macrocycles" 

  Kinney, Zacharias J.; Hartley, C. Scott

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