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Data archive for "Guest-driven control of folding in a crown-ether-functionalized ortho-phenylene"

dc.contributor.authorPeddi, Sumalatha
dc.contributor.authorBookout, Molly C.
dc.contributor.authorVemuri, Gopi Nath
dc.contributor.authorHartley, C. Scott
dc.date.accessioned2022-01-18T20:59:25Z
dc.date.available2022-01-18T20:59:25Z
dc.identifier.otherPeddi, S.; Bookout, M. C.; Vemuri, G. N.; Hartley, C. S. Guest-driven control of folding in a crown-ether-functionalized ortho-phenylene. J. Org. Chem. 2022, DOI: 10.1021/acs.joc.1c02605en_US
dc.identifier.urihttp://hdl.handle.net/2374.MIA/6803
dc.description.abstractA crown-ether-functionalized o-phenylene tetramer has been synthesized and coassembled with monotopic and ditopic, achiral and chiral secondary ammonium ion guests. NMR spectroscopy shows that the o-phenylene forms both 1:1 and 1:2 complexes with monotopic guests while remaining well-folded. Binding of an elongated ditopic guest, however, forces the o-phenylene to misfold by pulling the terminal rings apart. A chiral ditopic guest biases the o-phenylene twist sense.en_US
dc.relation.isversionof10.1021/acs.joc.1c02605en_US
dc.rightsAttribution 3.0 United States*
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/us/*
dc.titleData archive for "Guest-driven control of folding in a crown-ether-functionalized ortho-phenylene"en_US
dc.typeJournal Articleen_US
dc.date.published2022


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  • Hartley, Scott
    Dr. Scott Hartley - Professor, Chemistry & Biochemistry

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Attribution 3.0 United States
Except where otherwise noted, this item's license is described as Attribution 3.0 United States